SYNTHESIS OF A NOVEL DINUCLEAR MIXED FLUORODIOXOURANATE(VI), [(UO2)(2)(C5H7O2)F-7(H2O)(2)](4-) - THERMAL ROUTE TO NH4[UO2F3(H2O)]

Authors
BHATTACHARJEE CR ROY AKD
Citation
Cr. Bhattacharjee et Akd. Roy, SYNTHESIS OF A NOVEL DINUCLEAR MIXED FLUORODIOXOURANATE(VI), [(UO2)(2)(C5H7O2)F-7(H2O)(2)](4-) - THERMAL ROUTE TO NH4[UO2F3(H2O)], Journal of fluorine chemistry, 87(1), 1998, pp. 41-44
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
87
Issue
1
Year of publication
1998
Pages
41 - 44
Database
ISI
SICI code
0022-1139(1998)87:1<41:SOANDM>2.0.ZU;2-4
Abstract
Novel dinuclear complex species A(4)[(UO2)(2)(C5H7O2)F-7(H2O)(2)]. 5H( 2)O (A=NH4 or K) have been synthesised from the interaction of UO3 and AHF(4) (A=NH4 or K) in the presence of acetylacetone (C5H8O2). Spectr al evidence for terminal and bridging fluorides are provided. Thermogr avimetric study augmented the two different fluoride binding modes. Th ermal access to an oxofluorouranate (VI), NH4[UO2F3(H2O)], species is demonstrated. (C) 1998 Elsevier Science S.A.