SYNTHESIS OF POLYFLUOROALKYLATED 1,4-DIAZINOLS AND 1,4-OXAZINOLS USING POLYFLUORO-2,3-EPOXYALKANES32+13

Authors
SALOUTINA LV ZAPEVALOV AY KODESS MI SALOUTIN VI
Citation
Lv. Saloutina et al., SYNTHESIS OF POLYFLUOROALKYLATED 1,4-DIAZINOLS AND 1,4-OXAZINOLS USING POLYFLUORO-2,3-EPOXYALKANES32+13, Journal of fluorine chemistry, 87(1), 1998, pp. 49-55
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
87
Issue
1
Year of publication
1998
Pages
49 - 55
Database
ISI
SICI code
0022-1139(1998)87:1<49:SOP1A1>2.0.ZU;2-2
Abstract
It has been found that the reactions of polyfluoro-2,3-epoxyalkanes wi th ethylenediamine and 2-aminoethanol yield 2,3-di(polyfluoroalkyl)- 1 ,5,6-trihydro-1,4-diazin-2-ols and -di(polyfluoroalkyl)-5,6-dihydro-1, 4-oxazin-2-ols, respectively. In the case of unsymmetrical oxiranes mi xtures of regioisomeric heterocyclic compounds have been obtained. The se reactions were found to give some by products-N,N'-bis(polyfluoroac yl) ethylenediamines and N-polyfluoroacyl-2-aminoethanols. (C) 1998 El sevier Science S.A.