FLUORINATION OF OLEFINS WITH PHSEF3, PHSEF5 AND PHTEF5

Authors
LERMONTOV SA ZAVORIN SI BAKHTIN IV PUSHIN AN ZEFIROV NS STANG PJ
Citation
Sa. Lermontov et al., FLUORINATION OF OLEFINS WITH PHSEF3, PHSEF5 AND PHTEF5, Journal of fluorine chemistry, 87(1), 1998, pp. 75-83
Citations number
51
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
87
Issue
1
Year of publication
1998
Pages
75 - 83
Database
ISI
SICI code
0022-1139(1998)87:1<75:FOOWPP>2.0.ZU;2-G
Abstract
Phenyselenium trifluoride, PhSeF3 (PSTF) either oxidatively difluorina tes or selenofluorinates olefins, depending on their structures. The p entafluorides PhSeF5 and PhTeF5 appear to be effective difluorinating reagents, affording 1,2-difluoroalkanes from olefins. (C) 1998 Elsevie r Science S.A.