PREPARATION AND REACTIONS OF 2,4,6-TRIS(TRIFLUOROMETHYL)PHENYLAMINE

Authors
AHLEMANN JT ROESKY HW NOLTEMEYER M SCHMIDT HG MARKOVSKY LN SHERMOLOVICH YG
Citation
Jt. Ahlemann et al., PREPARATION AND REACTIONS OF 2,4,6-TRIS(TRIFLUOROMETHYL)PHENYLAMINE, Journal of fluorine chemistry, 87(1), 1998, pp. 87-90
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
87
Issue
1
Year of publication
1998
Pages
87 - 90
Database
ISI
SICI code
0022-1139(1998)87:1<87:PARO2>2.0.ZU;2-B
Abstract
Starting from RfH (1) [R-f=1,3,5-tris(trifluoromethyl)phenyl] RfNH2 (6 ) is obtained in a four-step synthesis. The amine 6 reacts with chloro trimethylsilane in the presence of DBU (1,8-diazabicyclo(5,4,0)undec-7 -ene) forming the monosilylated and the bissilylated amines 7 and 8. T he potassium salt of 7 reacts with SiCl4 yielding RfN(SiCl3), (10). Th e single crystal X-ray structure of 10 is reported. (C) 1998 Elsevier Science S.A.