A STUDY ON THE TERNARY-SYSTEM OF LA(CLO4) 3 BAPHDCA - H2O AT 30-DEGREES-C AND THE PREPARATION AND CHARACTERIZATION OF LA(BAPHDCA)(2)(CLO4)(3)CENTER-DOT-4H(2)O

Authors
CUI B TANG ZX LIANG HB GUO ZZ CHEN KX
Citation
B. Cui et al., A STUDY ON THE TERNARY-SYSTEM OF LA(CLO4) 3 BAPHDCA - H2O AT 30-DEGREES-C AND THE PREPARATION AND CHARACTERIZATION OF LA(BAPHDCA)(2)(CLO4)(3)CENTER-DOT-4H(2)O, Huaxue xuebao, 56(2), 1998, pp. 166-170
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Huaxue xuebao → ACNP
ISSN journal
05677351
Volume
56
Issue
2
Year of publication
1998
Pages
166 - 170
Database
ISI
SICI code
0567-7351(1998)56:2<166:ASOTTO>2.0.ZU;2-C
Abstract
Solubility and refractive indexes of the saturated solutions of the ti tled system at 30 degrees C have been studied and the corresponding eq uilibrium diagram and refractive index diagram were constructed. Both solubility curves and refractive index curves of the system consist of three branches, corresponding to BAPHDCA, La(BAPHDCA)(2)(ClO4)(3) . 4 H(2)O and La(ClO4)(3) . 8H(2)O respectively. La(BAPHDCA)(2) (ClO4)(3) . 4H(2)O is a new compound. It was characterized by IR spectra, TG-DTG , X-ray powder diffraction,as well as chemical and elemental analyses.