PROTON-CONDUCTING POLYMERS DERIVED FROM POLY(ETHER-ETHERKETONE) AND POLY(4-PHENOXYBENZOYL-1,4-PHENYLENE)

Authors
KOBAYASHI T RIKUKAWA M SANUI K OGATA N
Citation
T. Kobayashi et al., PROTON-CONDUCTING POLYMERS DERIVED FROM POLY(ETHER-ETHERKETONE) AND POLY(4-PHENOXYBENZOYL-1,4-PHENYLENE), Solid state ionics, 106(3-4), 1998, pp. 219-225
Citations number
19
Categorie Soggetti
Physics, Condensed Matter","Chemistry Physical
Journal title
Solid state ionics → ACNP
ISSN journal
01672738
Volume
106
Issue
3-4
Year of publication
1998
Pages
219 - 225
Database
ISI
SICI code
0167-2738(1998)106:3-4<219:PPDFPA>2.0.ZU;2-2
Abstract
henylene-oxy-1,4-phenylene-carbonyl-1,4-phenylene) (PEEK) and poly(4-p henoxybenzoyl-1,4-phenylene, Poly-X 2000) (PPBP), were sulfonated with sulfuric acid by incorporating sulfonic acid moieties in order to con vert these polymers to proton-conducting polymers. The sulfonated poly mers containing 65 mol% sulfonic acid showed a high proton-conductivit y of 10(-2)-10(-4) S cm(-1) at room temperature. Sulfonated PPBP showe d a much higher and more stable proton conductivity than sulfonated PE EK, which is in agreement with the strong water absorption of the form er compound.