Authors
Citation
B. Brzezinski et al., PROTON-TRANSFER REACTIONS FROM SOME DIARYLCYANOMETHANES TO CIS 1,2-BIS(DIETHYLAMINOMETHYL)CYCLOHEXANE IN ACETONITRILE, Journal of molecular structure, 442(1-3), 1998, pp. 153-160
Citations number
17
Categorie Soggetti
Chemistry Physical
Journal title
ISSN journal
00222860
Volume
442
Issue
1-3
Year of publication
1998
Pages
153 - 160
Database
ISI
SICI code
0022-2860(1998)442:1-3<153:PRFSDT>2.0.ZU;2-7
Abstract
Deprotonation of 4-nitrophenyl-phenylcyanomethane and 4-bromophenyl-4-
nitrophenylcyanomethane by cis 1,2-bis(diethylaminomethyI)cyclohexane
(DEAMCH) base with proton sponge-like character in acetonitrile is stu
died by kinetic as well as FT-IR spectroscopic methods. The mechanism
of the proton transfer reaction is proposed and compared with those of
other proton sponge bases. (C) 1998 Elsevier Science B.V.