RESOLUTION OF 2-PHENOXY-1-PROPANOLS BY PSEUDOMONAS SP. LIPASE-CATALYZED HIGHLY ENANTIOSELECTIVE TRANSESTERIFICATION - INFLUENCE OF REACTIONCONDITIONS ON THE ENANTIOSELECTIVITY TOWARD PRIMARY ALCOHOLS

Authors
MIYAZAWA T YUKAWA T UEJI S YANAGIHARA R YAMADA T
Citation
T. Miyazawa et al., RESOLUTION OF 2-PHENOXY-1-PROPANOLS BY PSEUDOMONAS SP. LIPASE-CATALYZED HIGHLY ENANTIOSELECTIVE TRANSESTERIFICATION - INFLUENCE OF REACTIONCONDITIONS ON THE ENANTIOSELECTIVITY TOWARD PRIMARY ALCOHOLS, Biotechnology letters, 20(3), 1998, pp. 235-238
Citations number
16
Categorie Soggetti
Biothechnology & Applied Migrobiology
Journal title
Biotechnology letters → ACNP
ISSN journal
01415492
Volume
20
Issue
3
Year of publication
1998
Pages
235 - 238
Database
ISI
SICI code
0141-5492(1998)20:3<235:RO2BPS>2.0.ZU;2-B
Abstract
2-Phenoxy-1-propanols were resolved using Pseudomonas sp. lipase with E (enantiomeric ratio) values of greater than or equal to 15. The enan tioselectivity was highest with vinyl acetate and became lower with th e chain length of the fatty acid moiety of acyl donors. It was improve d with decreasing temperature. A linear direct correlation was observe d between -RTlnE and the temperature of the reaction.