Chlorine in wood was determined in connection with the development of
a reference material (RM) of pentachlorophenol (PCP) in wood. The elem
ent was determined by photon activation analysis (PAA) using bremsstra
hlung of 19 MeV electrons from an electron linear accelerator. The ini
tial overall Cl content as well as the Cl remaining after extraction w
ith methanol and subsequent extraction with water were determined. Mor
eover, the PCP fractions in the organic and in the aqueous extracts we
re analyzed by gas chromatography (GC). The results show that at least
three quarters of the overall chlorine is bound in PCP and that PCP c
an be extracted to a high degree.