THE BRIGGS-RAUSCHER OSCILLATORY REACTIONS CATALYZED BY NICKEL MACROCYCLIC COMPLEXES

Authors
TIKHONOVA LP ROSOKHA SV BAKAY EA
Citation
Lp. Tikhonova et al., THE BRIGGS-RAUSCHER OSCILLATORY REACTIONS CATALYZED BY NICKEL MACROCYCLIC COMPLEXES, Reaction kinetics and catalysis letters, 63(1), 1998, pp. 129-136
Citations number
8
Categorie Soggetti
Chemistry Physical
Journal title
Reaction kinetics and catalysis letters → ACNP
ISSN journal
01331736
Volume
63
Issue
1
Year of publication
1998
Pages
129 - 136
Database
ISI
SICI code
0133-1736(1998)63:1<129:TBORCB>2.0.ZU;2-A
Abstract
The investigation of Briggs-Rauscher reactions (BRR) with nickel compl exes have shown that the range of the standard redox potentials of ERR catalysts is at least 0.7-1.7 V. An inner-sphere interaction of metal ions with hydrogen peroxide is a prerequisite of the oscillatory beha vior. The unique catalytic properties of the nickel compounds are prob ably due to their lower redox potential.