STUDY OF THE P2O5-MOO3 SYSTEM IN ACROLEIN OXIDATION

Authors
BONDAREVA VM ANDRUSHKEVICH TV PLYASOVA LM MAKSIMOVSKAYA RI CHUMACHENKO NN
Citation
Vm. Bondareva et al., STUDY OF THE P2O5-MOO3 SYSTEM IN ACROLEIN OXIDATION, Reaction kinetics and catalysis letters, 63(1), 1998, pp. 201-206
Citations number
12
Categorie Soggetti
Chemistry Physical
Journal title
Reaction kinetics and catalysis letters → ACNP
ISSN journal
01331736
Volume
63
Issue
1
Year of publication
1998
Pages
201 - 206
Database
ISI
SICI code
0133-1736(1998)63:1<201:SOTPSI>2.0.ZU;2-N
Abstract
Catalytic properties of the binary phosphorus-molybdenum system with M o/P = 3 - 24.5 in acrolein oxidation have been studied. The selectivit y to acrylic acid and carbon oxides practically does not depend on the chemical composition of the system, and the maximum activity is obser ved for Mo/P = 12. The catalytic properties of the system are determin ed by an X-ray amorphous phase, apparently molybdenyl phosphate.