CRYSTAL, MOLECULAR AND ELECTRONIC-STRUCTURE OF [REBR3(NO)(MECN)(PPH3)] COMPLEX

Authors
BARTCZAK TJ CZURAK W DZIEGIELEWSKI JO MACHURA B
Citation
Tj. Bartczak et al., CRYSTAL, MOLECULAR AND ELECTRONIC-STRUCTURE OF [REBR3(NO)(MECN)(PPH3)] COMPLEX, Polish Journal of Chemistry, 72(3), 1998, pp. 633-642
Citations number
46
Categorie Soggetti
Chemistry
Journal title
Polish Journal of Chemistry → ACNP
ISSN journal
01375083
Volume
72
Issue
3
Year of publication
1998
Pages
633 - 642
Database
ISI
SICI code
0137-5083(1998)72:3<633:CMAEO[>2.0.ZU;2-X
Abstract
A new rhenium nitrosyl complex has been synthesized and characterized by IR, UV-Vis, NMR (H-1 and P-31) and magnetochemical measurements. Th e crystal and molecular structure of [ReBr3(NO)(MeCN)(PPh3)] has been determined by X-rays. The Re atom is of six-coordinate distorted octah edral configuration and linear nitrosyl ligand is trans towards the ac etonitrile molecule.