V. Blanchet et A. Stolow, NONADIABATIC DYNAMICS IN POLYATOMIC SYSTEMS STUDIED BY FEMTOSECOND TIME-RESOLVED PHOTOELECTRON-SPECTROSCOPY, The Journal of chemical physics, 108(11), 1998, pp. 4371-4374
We investigate the use of time-resolved photoelectron spectroscopy for
studying nonadiabatic polyatomic dissociation dynamics. In particular
, we emphasize the importance of the electronic structure of the ioniz
ation continuum in interpreting the results and provide an experimenta
l example of these effects in the dissociation dynamics of the NO dime
r. (C) 1998 American Institute of Physics.