COMPLEXATION OF BORIC-ACID WITH THE N-METHYL-D-GLUCAMINE GROUP IN SOLUTION AND IN CROSS-LINKED POLYMER

N-Methylglucamine resin has been shown to be a good adsorbent for bera te or boric acid. Above ca. pH 6, the boron adsorbability of this resi n increased with a maximum around pH 9. The maximum distribution ratio was higher than 10(6), however, further increase in pH resulted in a decrease in the distribution ratio. The combination of distribution an d B-11 MAS NMR measurements revealed the formation of a 1:1 tetradenta te complex of B(OH)(4)(-) with the N-methylglucamine group. The calcul ated pH-dependence of boron adsorption agreed well with the experiment al results with respect to the -log [H+] values in the resin phase (no t in the external solution) estimated by P-31 NMR measurements. The ma ximum adsorption around pH 9 of the equilibrated solution is due to th e fact that the pH in the resin phase remains higher than that in the external solution. Therefore, B(OH)(3)/B(OH)(4)(-) is selectively conc entrated into the resin phase and by the dehydration condensation B(OH )(4)(-) forms the 1 :1 tetradentate complex with the anchor group. The overall formation constant of the complex was estimated to be 10(4.0/-0.1), Which was almost the same magnitude as that of the 1 : 1 monoc helate complex with an alpha,beta-diol site of N-methyl-D-glucamine (w hich is an analogue of the functional group of the resin) in aqueous s olutions of pH 5.1-7.4. However, the binding structures of each 1 : 1 complex with the N-methyl-D-glucamine group are quite different in the aqueous solution and in the crosslinked polymer.