THEORETICAL-STUDY OF SILSESQUIOXANE ORGANOMETALLIC COMPLEX STRUCTURE AND IR-SPECTRUM - II - INTERPRETATION OF THE IR-SPECTRUM

On the basis of the parameters identified in the first paper of this s eries of two, the spectral distribution curves of the absorption coeff icient in the IR spectral interval for a silsesquioxane organometallic complex were calculated, Good agreement with experimental data was ob tained, A detailed interpretation of the spectra was made, and it was shown that the most of the bands in the spectra are the result of supe rposition of a large number of vibrations, Conclusions about the struc ture of the investigated molecules were made. (C) 1998 Elsevier Scienc e B.V.