STEREOSELECTIVE SYNTHESIS OF A NEW OPTICALLY-ACTIVE PHOSPHINOACYLOXAZOLIDINONE VIA ENANTIOSELECTIVE HYDROGENATION

Authors
LEGENDRE P JEROME F BRUNEAU C DIXNEUF PH
Citation
P. Legendre et al., STEREOSELECTIVE SYNTHESIS OF A NEW OPTICALLY-ACTIVE PHOSPHINOACYLOXAZOLIDINONE VIA ENANTIOSELECTIVE HYDROGENATION, Chemical communications, (5), 1998, pp. 533-534
Citations number
17
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
5
Year of publication
1998
Pages
533 - 534
Database
ISI
SICI code
1359-7345(1998):5<533:SSOANO>2.0.ZU;2-8
Abstract
The preparation of a new optically active phosphinoacyloxazolidinone, based on the enantioselective hydrogenation of a 4-methylene-N-propion yloxazolidinone in the presence of [(R)-BINAP]Ru(O2CCF3)(2) catalyst f ollowed by stereoselective phosphinylation, is reported.