STRUCTURAL AUTHENTICATION OF AN N-FUNCTIONALIZED DISECONDARY DIPHOSPHANE

Authors
ANDREWS PC KING SJ RASTON CL ROBERTS BA
Citation
Pc. Andrews et al., STRUCTURAL AUTHENTICATION OF AN N-FUNCTIONALIZED DISECONDARY DIPHOSPHANE, Chemical communications, (5), 1998, pp. 547-548
Citations number
10
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
5
Year of publication
1998
Pages
547 - 548
Database
ISI
SICI code
1359-7345(1998):5<547:SAOAND>2.0.ZU;2-E
Abstract
The reaction of RPCl2 [R = (6-Me-2-pyridyl)(SiMe3)(2)C-] with LiAlH4 i n Et2O gives the novel N-functionalised disecondary diphosphane compou nd [ROT)P-P(H)R] rather than the expected phosphorus dihydride complex RPH2; the meso and rac isomers of the diphosphane crystallise separat ely with the meso isomer being structurally authenticated.