AGGREGATION OF LITHIUM AND MIXED THALLIUM(I)-LITHIUM AMIDES THROUGH ETA(3)-PI-ARENE AND ETA(6)-PI-ARENE INTERACTIONS IN THE SOLID

Authors
HELLMANN KW GALKA C GADE LH STEINER A WRIGHT DS KOTTKE T STALKE D
Citation
Kw. Hellmann et al., AGGREGATION OF LITHIUM AND MIXED THALLIUM(I)-LITHIUM AMIDES THROUGH ETA(3)-PI-ARENE AND ETA(6)-PI-ARENE INTERACTIONS IN THE SOLID, Chemical communications, (5), 1998, pp. 549-550
Citations number
21
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
5
Year of publication
1998
Pages
549 - 550
Database
ISI
SICI code
1359-7345(1998):5<549:AOLAMT>2.0.ZU;2-I
Abstract
The mixed Li-Tl amide [C10H6{N[Li(thf)(2)]SiMe3}{N(Tl)SiMe3}] has been synthesized and shown to aggregate via eta(6)-arene-thallium coordina tion in the solid; a related pattern of aggregation is found for the p artially solvated homometallic Li amide [C10H6{N[Li(thf)]SiMe3}{N(Li)S iMe3}] which displays an unusual eta(3)-arene-lithium interaction.