FIRST CHARACTERIZATION OF ZIRCONIUM ENOLATE RADICAL CATIONS IN SOLUTION AND THEIR MESOLYTIC BOND-CLEAVAGE TO ZIRCONOCENE CATIONS

Authors
SCHMITTEL M SOLLNER R
Citation
M. Schmittel et R. Sollner, FIRST CHARACTERIZATION OF ZIRCONIUM ENOLATE RADICAL CATIONS IN SOLUTION AND THEIR MESOLYTIC BOND-CLEAVAGE TO ZIRCONOCENE CATIONS, Chemical communications, (5), 1998, pp. 565-566
Citations number
31
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
5
Year of publication
1998
Pages
565 - 566
Database
ISI
SICI code
1359-7345(1998):5<565:FCOZER>2.0.ZU;2-K
Abstract
Zirconocene enolate radical cations are generated and characterised in solution for the first time; the sterically congested radical cations undergo a mesolytic Zr-O bond cleavage process yielding zirconocene c ations, the kinetics of which are determined.