SYNTHESIS AND CRYSTAL-STRUCTURES OF P-HALOGENO(IMINO)METHYLENEPHOSPHORANES X-P(=NTBU(3)C(6)H(2))=C(SIME3)(2) (X=CL, BR, I)

Authors
RUBAN A NIEGER M NIECKE E
Citation
A. Ruban et al., SYNTHESIS AND CRYSTAL-STRUCTURES OF P-HALOGENO(IMINO)METHYLENEPHOSPHORANES X-P(=NTBU(3)C(6)H(2))=C(SIME3)(2) (X=CL, BR, I), EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, (1), 1998, pp. 83-85
Citations number
34
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY → ACNP
ISSN journal
14341948
Issue
1
Year of publication
1998
Pages
83 - 85
Database
ISI
SICI code
1434-1948(1998):1<83:SACOP>2.0.ZU;2-S
Abstract
The iminophosphane (Me3Si)(3)C-P=N-Mes (1) reacts with iodine to form the imino(methylene)phosphorane I-P(=N-Mes)=C(SiMe3)(2) (2). Upon su bsequent treatment with AgCl, the corresponding chloro derivative 3 is obtained.