A number of unsaturated poly(amid obenzimidazoles) based on itaconic a
cid dichloroanhydride and diamines bearing benzimidazole rings were sy
nthesized by low-temperature polycondensation in solution. Linear unsa
turated poly(amidobenzimidazoles) an soluble in organic solvents, have
a large difference between the softening temperature send the degrada
tion temperature, and are capable of producing cross-linked, three-dim
ensional products that exhibit high thermal stability and good mechani
cal properties upon thermal processing.