As part of a large, interdisciplinary program investigating the electr
omagnetic properties of sea ice, we made spectral measurements of the
albedo, reflectance, and Stokes vector of the reflected radiance field
. The overall program encompassed observations of sea ice physical pro
perties, optical properties and microwave properties, plus an extensiv
e modeling effort. Measurements were made of an evolution sequence inc
luding young sea ice, pancake ice, snow-covered ice, first-year ice, a
nd ponded ice. The effects of surface roughness were investigated by a
rtificially roughening part of a 31-cm-thick, smooth, young ice sheet.
Spectral and total albedos were sensitive to surface conditions, cons
istent with earlier studies. Stokes vector observations exhibited the
greatest variability in the plane of incidence of the solar beam. Refl
ectances at 0 degrees azimuth increased sharply with zenith angle. Smo
other surfaces, such as melt ponds, pancakes and bare ice, exhibited a
larger increase than the snow-covered cases with their ''rougher'' su
rfaces. Since the solar zenith angle was close to Brewster's angle, sp
ecularly reflected light was highly polarized. In the ''smooth'' ice c
ases, there was significant polarization associated with the increase
in reflectance, implying a substantial contribution from specular refl
ection. This contribution was greater at longer wavelengths, where spe
cular reflection was a larger component of the reflected radiance. Awa
y from the plane of incidence, the Stokes vector showed little angular
variation, and the reflected light at these angles was largely unpola
rized.