This paper deals with the raining of particles from an interface betwe
en a dense fluidized phase and a gas phase with the fluidized phase up
permost. Such interfaces occur at the upper surfaces of gas bubbles an
d slugs in fluidized beds. Particle rain in these cases would enhance
contact between gas and particles within the bubbles and slugs. The ri
se velocities of single square-nosed slugs injected in incipiently flu
idized beds of different diameters were measured. Relatively small col
umns of internal diameters of 0.0125, 0.019 and 0.0254 m were employed
in the experiments; In such beds, square-nosed slugs are formed which
span the entire cross-section of the beds and rise entirely due to ra
ining of particles from their top surfaces. Since the upper surface of
such slugs is flat, their motion can be analyzed using the one-dimens
ional hydrodynamic theory. Glass ballotini and sand of different sizes
were used as bed particles. Comparison of theory and experiment has e
nabled the determination of the dimensionless gradient diffusivity cha
racterizing the motion of particles induced by a gradient in the void
fraction. The results confirm the scaling proposed by Batchelor (1988)
. The use of the calculated gradient diffusivity in the criterion for
stability of a gas fluidized bed predicts the systems under considerat
ion to be always unstable.