RADIATIONLESS DEACTIVATION OF EXCITED MOLECULES OF 4-AMINONAPHTHALIMIDES

The effects of alkylation of the 4-amino group, polarity and viscosity of a solvent, and temperature on the fluorescence of N-(2,4-dimethylp henyl)imides of 4-amino-1,8-naphthalenedicarboxylic acid were studied. A decrease in the temperature and polarity of a solvent and an increa se in its viscosity cause the rate of radiationless deactivation of 4- dimethylaminonaphthalimide to decrease and have almost no effect on th e rate of emissive deactivation of excited state. The abnormally low e fficiency of fluorescence of 4-dimethylaminonaphthalimide in polar low -viscosity media at room temperature is associated with the formation of a nonfluorescent charge-transfer state. The increase in the sate of radiationless deactivation of 4-aminonaphthalimide in the alkylation of its amino group is associated with the increase in its electron-don or ability.