ELECTROCHEMICAL ACTIVATION OF THE ALKYLATION OF GEI2 BY N-BUTYL BROMIDE AND METHYLCOBALT(III) BISDIMETHYLGLYOXIMATE

Authors
RAKHIMOV RD BUTIN KP
Citation
Rd. Rakhimov et Kp. Butin, ELECTROCHEMICAL ACTIVATION OF THE ALKYLATION OF GEI2 BY N-BUTYL BROMIDE AND METHYLCOBALT(III) BISDIMETHYLGLYOXIMATE, Russian chemical bulletin, 46(12), 1997, pp. 2044-2047
Citations number
13
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
46
Issue
12
Year of publication
1997
Pages
2044 - 2047
Database
ISI
SICI code
1066-5285(1997)46:12<2044:EAOTAO>2.0.ZU;2-K
Abstract
The mechanism of the alkylation of GeI2 by n-butyl bromide and methylc obalt(III) bisdimethylglyoximate in acetonitrile was studied using cyc lic voltammetry. The reaction with the methylcobalt complex occurs via anodic activation (oxidation of the methylcobalt complex), while the reaction with n-butyl bromide is initiated by cathodic activation (red uction of GeI2).