SOLID-STATE REACTIONS OF ORGANOMETALLIC ALDEHYDES WITH OPTICALLY-ACTIVE PRIMARY BETA-HYDROXYAMINES

Authors
KHRUSCHEVA NS LOIM NM SOKOLOV VI
Citation
Ns. Khruscheva et al., SOLID-STATE REACTIONS OF ORGANOMETALLIC ALDEHYDES WITH OPTICALLY-ACTIVE PRIMARY BETA-HYDROXYAMINES, Russian chemical bulletin, 46(12), 1997, pp. 2124-2126
Citations number
11
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
46
Issue
12
Year of publication
1997
Pages
2124 - 2126
Database
ISI
SICI code
1066-5285(1997)46:12<2124:SROOAW>2.0.ZU;2-P
Abstract
The solid-state reactions of crystalline ferrocenyl- and ruthenocenyla ldehydes with optically active primary beta-hydroxyamines were studied at similar to 20 degrees C. The yield of the products increases subst antially in the presence of K2CO3. The tautomeric equilibrium between imines and diastereomeric oxazolidines with the predominant formation of one of them is established in solutions of the products in CDCl3.