CONCENTRATION OSCILLATIONS IN THE CONDENSATION OF ORGANOSILANOLS

Authors
IVANOV PV MASLOVA VI BONDAREVA NG YUREVA OA KOZLOVA NV CHERNYSHEV EA ODINTSOV KY ZYKUNOVA EA
Citation
Pv. Ivanov et al., CONCENTRATION OSCILLATIONS IN THE CONDENSATION OF ORGANOSILANOLS, Russian chemical bulletin, 46(12), 1997, pp. 2138-2141
Citations number
5
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
46
Issue
12
Year of publication
1997
Pages
2138 - 2141
Database
ISI
SICI code
1066-5285(1997)46:12<2138:COITCO>2.0.ZU;2-J
Abstract
Auto-oscillations were discovered by TLC in a study of the condensatio n of RR'Si(OH)(2) (R = R' = Me, Et, Ph; R = Me, R' = CH2=CH, Ph, OH) i n aqueous organic solvents in the pH range -1-15 up to large degrees o f conversion of the monomer (70-100%). The process is characterized by complicated profiles of the kinetic curves containing sections of acc eleration and deceleration of the reaction. The nonequilibrium charact er of the process was established. It was assumed that the phenomena o bserved arise as a result of association of the monomer and oligomers during the reaction.