A SIMPLE SYNTHESIS OF YL-1,1,1-TRIFLUORO(TRICHLORO)HEPTA-3,5-DIEN-2-ONES AND -DIMETHYL-6-TRIFLUOROMETHYL-2,3-DIHYDRO-4-PYRIDONE

Authors
SOSNOVSKIKH VY
Citation
Vy. Sosnovskikh, A SIMPLE SYNTHESIS OF YL-1,1,1-TRIFLUORO(TRICHLORO)HEPTA-3,5-DIEN-2-ONES AND -DIMETHYL-6-TRIFLUOROMETHYL-2,3-DIHYDRO-4-PYRIDONE, Russian chemical bulletin, 46(12), 1997, pp. 2145-2146
Citations number
3
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
46
Issue
12
Year of publication
1997
Pages
2145 - 2146
Database
ISI
SICI code
1066-5285(1997)46:12<2145:ASSOY>2.0.ZU;2-7
Abstract
Treatment of 6-trifluoro(trichloro)methyl-2,3-dihydro-4-pyrones with a mmonia gives -amino-1,1,1-trifluoro(trichloro)-6-methylhepta-3, 5-dien -2-ones. Under similar conditions 1-trifluoro-2-hydroxy-6-methylhepta- 2,5-dien-4-one and -1,1,1-trifluoro-2-hydroxy-6-methylhept-2-en-4-one cyclize into dimethyl-6-trifluoromethyl-2,3-dihydro-4-pyridone.