We demonstrate a new application of photoemission electron microscopy
(PEEM) for the investigation of Schottky contacts. As an example we ha
ve investigated the changes in contrast in PEEM images when silver is
deposited on a lateral p-n diode structure on a Si(100) surface. In ag
reement with recent studies by other groups, we find three-dimensional
island growth in the multilayer regime at low temperatures when silve
r is grown on the clean silicon surface. We also find three-dimensiona
l growth when silver is deposited on a thin, wet chemically formed oxi
de layer. In both cases, the p-doped regions appear brighter than the
n-doped regions in the PEEM image. When the silver layer is heated to
900 degrees C the islands disappear. For the case of silver on the oxi
de-free Si(100) surface, the p regions remain brighter than the n regi
ons. In the case of silver growth on an intermediate oxide layer, the
contrast in the image changes dramatically during heating. The experim
ental results are interpreted in terms of the band bending caused by i
nterface states. (C) 1998 Elsevier Science B.V.