SYNTHESIS AND CRYSTAL-STRUCTURE OF THE LA NTHANUM TITANATE TELLURATE LATI(TI0.25TE0.75)O-6 AND ITS RELATIONSHIP TO PBSB2O6 AND SR(MNTE)O-6

Authors
WULFF L MULLERBUSCHBAUM H
Citation
L. Wulff et H. Mullerbuschbaum, SYNTHESIS AND CRYSTAL-STRUCTURE OF THE LA NTHANUM TITANATE TELLURATE LATI(TI0.25TE0.75)O-6 AND ITS RELATIONSHIP TO PBSB2O6 AND SR(MNTE)O-6, Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 53(2), 1998, pp. 149-152
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
53
Issue
2
Year of publication
1998
Pages
149 - 152
Database
ISI
SICI code
0932-0776(1998)53:2<149:SACOTL>2.0.ZU;2-S
Abstract
Single crystals of LaTi(Ti0.25Te0.75)O-6 have been prepared by solid s tate reactions. X-ray investigations led to trigonal symmetry, space g roup C-3(1)-P3, a = 5.141(10), c = 5.218(10) Angstrom, Z = 1. The comp ound is characterized by a predominantly ordered distribution of Ti4and Te6+. Typical features of the crystal structure are staggered laye rs containing edge connected TiO6 and (Ti,Te)O-6 octahedra. The layers are connected by La3+ ions receiving an octahedral coordination by th e surrounding oxygen ions. The relationships to the PbSb2O6 type and t he recently described compound Sr(MnTe)O-6 are discussed.