SYNTHESIS AND CRYSTAL-STRUCTURE OF [H2NME 2](-)()[(ME2NH)(2)TICL4]()

Authors
BETTENHAUSEN R MILIUS W SCHNICK W
Citation
R. Bettenhausen et al., SYNTHESIS AND CRYSTAL-STRUCTURE OF [H2NME 2](-)()[(ME2NH)(2)TICL4](), Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 53(2), 1998, pp. 239-241
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
53
Issue
2
Year of publication
1998
Pages
239 - 241
Database
ISI
SICI code
0932-0776(1998)53:2<239:SACO[2>2.0.ZU;2-5
Abstract
The title compound has been synthesized as a green solid by the reacti on of MeCl2 SiNHSiMe3 and Ti(NMe2)(4) in CH2Cl2. The crystal structure was determined by single crystal X-ray methods at room temperature (C 2/c, a = 1825,7(4), b = 909,9(2), c = 1116,1(2) pm, beta = 125,09(3)de grees, Z = 4, R1 = 0,047, wR2 = 0,147) to be an ionic salt [H2NMe2](+) [(Me2NH)(2)TiCl4](-). The central titanium(III) atom of the anion is bound to four Cl atoms and weakly coordinated by two Me2NH ligands.