ELECTROCATALYTIC OXIDATION OF AMINES TO NITRILES ON A TEMPO-MODIFIED GRAPHITE FELT ELECTRODE (TEMPO = 2,2,6,6-TETRAMETHYLPIPERIDIN-1-YLOXYL)

Citation
Y. Kashiwagi et al., ELECTROCATALYTIC OXIDATION OF AMINES TO NITRILES ON A TEMPO-MODIFIED GRAPHITE FELT ELECTRODE (TEMPO = 2,2,6,6-TETRAMETHYLPIPERIDIN-1-YLOXYL), Journal of the Chinese Chemical Society, 45(1), 1998, pp. 135-138
Citations number
10
Categorie Soggetti
Chemistry
ISSN journal
00094536
Volume
45
Issue
1
Year of publication
1998
Pages
135 - 138
Database
ISI
SICI code
0009-4536(1998)45:1<135:EOOATN>2.0.ZU;2-7
Abstract
Preparative electrocatalytic oxidation of amines to nitriles was succe ssfully achieved on a poly (acrylic acid)-coated graphite felt electro de immobilizing 4-amino-2,2,6,6-tetramethylpiperidin-1-yloxyl in high selectivity (> 95%) and high current efficiency (> 92%).