SYNTHESIS OF CARBON-CHAIN TETHERED BISTETRAOXA-CAGE COMPOUNDS

Authors
CHERN JH WU HJ WANG SL LIAO FL
Citation
Jh. Chern et al., SYNTHESIS OF CARBON-CHAIN TETHERED BISTETRAOXA-CAGE COMPOUNDS, Journal of the Chinese Chemical Society, 45(1), 1998, pp. 139-144
Citations number
66
Categorie Soggetti
Chemistry
Journal title
Journal of the Chinese Chemical Society → ACNP
ISSN journal
00094536
Volume
45
Issue
1
Year of publication
1998
Pages
139 - 144
Database
ISI
SICI code
0009-4536(1998)45:1<139:SOCTBC>2.0.ZU;2-W
Abstract
Carbon-chain tethered bistetraoxa-cage compounds 7a-c and 8a-c were sy nthesized from 2-methyl-furan in a four-step sequence. They were obtai ned from ozonolysis of the syn bisadducts 5a-c and the anti bisadducts 6a-c in dichloromethane at -78 degrees C followed by reduction with d imethyl sulfide. The structure of the anti bisadduct 6a was proven by X-ray crystallographical analysis.