N. Boudin et al., CONSTRAINTS ON THE ABUNDANCES OF VARIOUS MOLECULES IN INTERSTELLAR ICE - LABORATORY STUDIES AND ASTROPHYSICAL IMPLICATIONS, Astronomy and astrophysics, 331(2), 1998, pp. 749-759
Ethane, acetylene, ethanol, hydrazine and hydrogen peroxyde are either
predicted by theoretical models to be abundant in the icy mantles on
grains in dense clouds, or were found to be produced by comets. We pre
sent measurements of the spectra of these species embedded in astrophy
sically relevant ice matrices. Additionally, we obtained the spectrum
of the hydrozonium ion (N2H5+) which could be produced by activationle
ss acid-base reactions. The laboratory results are compared to the ISO
and ground-based spectra of NGC 7538:IRS 9. Strict upper-limits compa
red to the solid water could be found for ethane, ethanol and hydrogen
peroxyde of < 0.4%, < 1.2%, and < 6.1%, respectively. These results g
ive some important information on the relationship between cometary an
d interstellar ices and on the nature of grain surface reactions.