FIRST CHEMICAL-TRANSFORMATIONS OF LANTHANIDE BOROHYDRIDE COMPOUNDS - SYNTHESIS AND CRYSTAL-STRUCTURES OF [(ETA-C8H8)ND(BH4)(THF)](2) AND [(ETA-C8H8)ND(THF)(4)][BPH4]

Authors
CENDROWSKIGUILLAUME SM NIERLICH M LANCE M EPHRITIKHINE M
Citation
Sm. Cendrowskiguillaume et al., FIRST CHEMICAL-TRANSFORMATIONS OF LANTHANIDE BOROHYDRIDE COMPOUNDS - SYNTHESIS AND CRYSTAL-STRUCTURES OF [(ETA-C8H8)ND(BH4)(THF)](2) AND [(ETA-C8H8)ND(THF)(4)][BPH4], Organometallics, 17(5), 1998, pp. 786-788
Citations number
46
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
17
Issue
5
Year of publication
1998
Pages
786 - 788
Database
ISI
SICI code
0276-7333(1998)17:5<786:FCOLBC>2.0.ZU;2-X
Abstract
Reaction of Nd(BH4)(3)(THF)(3) with K2COT (COT = eta-C8H8) in tetrahyd rofuran (THF) gave the first (cyclooctatetraene)lanthanide borohydride , (COT)Nd(BH4)(THF)(2) (1). By treatment with NHEt3BPh4, 1 was transfo rmed into [(COT)Nd(THF)(4)][BPh4] (3), a unique example of a (cyclooct atetraene)lanthanide cation; both 1 and 3 gave (COT)Nd(Cp)(THF) (Cp* = eta-C5Me5) upon. reaction with KCp.