REACTIONS OF A CHELATED CYCLOPENTADIENYLCOBALT(I) COMPLEX WITH 3,3-DISUBSTITUTED CYCLOPROPENES - FORMATION OF ISOPRENE, VINYLCARBENE, AND 1-PHOSPHADIENE LIGANDS AT THE METAL

Authors
FOERSTNER J KAKOSCHKE A STELLFELDT D BUTENSCHON H WARTCHOW R
Citation
J. Foerstner et al., REACTIONS OF A CHELATED CYCLOPENTADIENYLCOBALT(I) COMPLEX WITH 3,3-DISUBSTITUTED CYCLOPROPENES - FORMATION OF ISOPRENE, VINYLCARBENE, AND 1-PHOSPHADIENE LIGANDS AT THE METAL, Organometallics, 17(5), 1998, pp. 893-896
Citations number
33
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
17
Issue
5
Year of publication
1998
Pages
893 - 896
Database
ISI
SICI code
0276-7333(1998)17:5<893:ROACCC>2.0.ZU;2-O
Abstract
-butylphosphanyl-P-ethyl)cyclopentadienylcobalt(I) complexes 1 and 2 w ere treated with 3,3-disubstituted cyclopropenes to give isoprene and vinylcarbene complexes. The diphenylvinylcarbene complex reacted with tert-butylphosphaethyne to give unusual coupling products.