ATTEMPTED STEREOCONTROL AT C-2' OF STRIGOL-TYPE COMPOUNDS BY A MICHAEL REACTION ELIMINATION APPROACH/

Authors
ROHRIG S HENNIG L FINDEISEN M WELZEL P FRISCHMUTH K MARX A PETROWITSCH T KOLL P MULLER D MAYERFIGGE H SHELDRICK WS
Citation
S. Rohrig et al., ATTEMPTED STEREOCONTROL AT C-2' OF STRIGOL-TYPE COMPOUNDS BY A MICHAEL REACTION ELIMINATION APPROACH/, Tetrahedron, 54(14), 1998, pp. 3413-3438
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
54
Issue
14
Year of publication
1998
Pages
3413 - 3438
Database
ISI
SICI code
0040-4020(1998)54:14<3413:ASACOS>2.0.ZU;2-E
Abstract
By a Michael addition/nucleophilic substitution/elimination sequence t he stereocontrol at C-2' in strigol-typed compounds is in principle po ssible. However, the method is unsuitable for practical application si nce it has been shown that a stereolabile intermediate is involved. (C ) 1998 Elsevier Science Ltd. All rights reserved.