Bl. Hurrell et Re. Cameron, PHYSICAL AGING AND THE EMBRITTLEMENT OF POLY(HYDROXYBUTYRATE) ON STORAGE - A TIME-RESOLVED SMALL-ANGLE X-RAY-SCATTERING STUDY, Polymer international, 45(3), 1998, pp. 308-312
Time resolved small angle X-ray scattering is used to probe the micros
tructural changes occurring in a sample of poly(hydroxybutyrate), aged
at room temperature, during a heating cycle designed to reverse any p
hysical ageing. Evidence for the reversal of physical ageing is seen,
but is unlikely to account for all the changes in mechanical propertie
s in this polymer on storage at room temperature. (C) 1998 SCI.