PALLADIUM-CATALYZED COUPLING REACTIONS OF 1-BROMOADAMANTANE WITH STYRENES AND ARENES

Authors
BRASE S WAEGELL B DEMEIJERE A
Citation
S. Brase et al., PALLADIUM-CATALYZED COUPLING REACTIONS OF 1-BROMOADAMANTANE WITH STYRENES AND ARENES, Synthesis, (2), 1998, pp. 148-152
Citations number
30
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis → ACNP
ISSN journal
00397881
Issue
2
Year of publication
1998
Pages
148 - 152
Database
ISI
SICI code
0039-7881(1998):2<148:PCRO1W>2.0.ZU;2-A
Abstract
The palladium-catalyzed reaction of 1-bromoadamantane (1-Br) with styr ene and donor-substituted styrenes gave the corresponding Heck-type co upling products 3a and b, and 5a and b in moderate yields (15-41%), wh ile the reaction of 1-Br with various arenes 6a-p under palladium cata lysis gave the corresponding adamantyl-substituted arenes 7a-p in good to excellent yields (35-98%).