NOVEL CONVENIENT METHOD FOR THE SYNTHESIS OF N,N-BIS(TRIMETHYLSILYLOXY)ENAMINES

Authors
DILMAN AD TISHKOV AA LYAPKALO IM IOFFE SL STRELENKO YA TARTAKOVSKY VA
Citation
Ad. Dilman et al., NOVEL CONVENIENT METHOD FOR THE SYNTHESIS OF N,N-BIS(TRIMETHYLSILYLOXY)ENAMINES, Synthesis, (2), 1998, pp. 181-185
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis → ACNP
ISSN journal
00397881
Issue
2
Year of publication
1998
Pages
181 - 185
Database
ISI
SICI code
0039-7881(1998):2<181:NCMFTS>2.0.ZU;2-N
Abstract
Both primary and secondary aliphatic nitro compounds 1 were found to r eact with two equivalents of bromotrimethylsilane in the presence of t riethylamine followed by aqueous workup to give appropriate N,N-bis(tr imethylsilyloxy)enamines 3 in good isolated yields. Products 3, starti ng from some secondary and/or sterically hindered compounds 1, are syn thesized from the corresponding silyl nitronates 2.