SYNTHESIS AND CHARACTERIZATION OF UNSYMMETRICAL S-(PHOSPHINO-ARSINO)ETHENE)TETRACARBONYLMOLYBDENUM COMPLEXES - HYDROARSINATION REACTIONS OF(H3CC-CPPH2)MO(CO)(5) AND [H2C=C=CH(DBP)]MO(CO)(5) AND HYDROPHOSPHINATION REACTIONS OF (PH2ASCH2C-CH)MO(CO)(5)

Authors
MAITRA K CATALANO VJ CLARK J NELSON JH
Citation
K. Maitra et al., SYNTHESIS AND CHARACTERIZATION OF UNSYMMETRICAL S-(PHOSPHINO-ARSINO)ETHENE)TETRACARBONYLMOLYBDENUM COMPLEXES - HYDROARSINATION REACTIONS OF(H3CC-CPPH2)MO(CO)(5) AND [H2C=C=CH(DBP)]MO(CO)(5) AND HYDROPHOSPHINATION REACTIONS OF (PH2ASCH2C-CH)MO(CO)(5), Inorganic chemistry, 37(5), 1998, pp. 1105-1111
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
37
Issue
5
Year of publication
1998
Pages
1105 - 1111
Database
ISI
SICI code
0020-1669(1998)37:5<1105:SACOUS>2.0.ZU;2-O
Abstract
The base-catalyzed hydroarsination reactions of (H3CC=CPPh2)Mo(CO)(5) and [H2C=C=CH(DBP)]Mo(CO)(5) (DBP=dibenzophosphole) give several diffe rent products as a function of reaction conditions. These products hav e been characterized by elemental analyses, physical properties, H-1, C-13{H-1}, and P-31{H-1} NMR spectroscopy, and, in two cases, X-ray cr ystallography.