The Athabasca oil sands deposit in Alberta contains similar to 5 x 10(
9) m(3) of bitumen accessible by surface mining. During bitumen separa
tion from the mined ore, ultra-fine (<300 nm) aluminosilicate clays on
ly a few layers thick (U/F) are mobilized and become dispersed in the
process water. In this water containing dissolved salts from natural d
eposits, U/F are capable of forming thixotropic gels. The consequence
of this is the production of large volumes of mature fine tailings (MF
T) with a high water holding capacity. For mine planning purposes, the
objective of predicting and possibly mitigating MFT formation require
s an understanding of the colloidal behaviour of U/F particles in salt
solutions. In this work, photon correlation spectroscopy and the deut
erium NMR method are used to provide an insight into the U/F flee form
ation process. These results are correlated with conventional analysis
of settling data.