1,4-ANTI INDUCTION IN C-GLYCOSYLATION OF PENTOSE GLYCALS

Authors
HOSOKAWA S KIRSCHBAUM B ISOBE M
Citation
S. Hosokawa et al., 1,4-ANTI INDUCTION IN C-GLYCOSYLATION OF PENTOSE GLYCALS, Tetrahedron letters, 39(14), 1998, pp. 1917-1920
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
14
Year of publication
1998
Pages
1917 - 1920
Database
ISI
SICI code
0040-4039(1998)39:14<1917:1IICOP>2.0.ZU;2-3
Abstract
The C-glycosylation of pentose glycals with silylacetylenes or allylsi lanes via oxocarbenium ion intermediates proceeded under high regio-an d stereoselectivity giving the 1,4-anti products as the predominant pr oducts. (C) 1998 Elsevier Science Ltd. All rights reserved.