1,1,2,2-TETRAPHENYLDISILANE AS A DIVERSIFIED RADICAL REAGENT

Authors
YAMAZAKI O TOGO H MATSUBAYASHI S YOKOYAMA M
Citation
O. Yamazaki et al., 1,1,2,2-TETRAPHENYLDISILANE AS A DIVERSIFIED RADICAL REAGENT, Tetrahedron letters, 39(14), 1998, pp. 1921-1924
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
14
Year of publication
1998
Pages
1921 - 1924
Database
ISI
SICI code
0040-4039(1998)39:14<1921:1AADRR>2.0.ZU;2-Q
Abstract
Reactivity of 1,1,2,2-tetraphenyldisilane as a radical reagent in etha nol was studied in reduction of alkyl bromides, addition to olefin and alkylation onto heteroaromatic bases with alkyl bromides. The present organodisilane showed moderate to good reactivities for these three t ypes of radical reactions. (C) 1998 Elsevier Science Ltd. All rights r eserved.