PREPARATION OF A NOVEL INDIUM HYDRIDE AND APPLICATION TO PRACTICAL ORGANIC-SYNTHESIS

Authors
MIYAI T INOUE K YASUDA M SHIBATA I BABA A
Citation
T. Miyai et al., PREPARATION OF A NOVEL INDIUM HYDRIDE AND APPLICATION TO PRACTICAL ORGANIC-SYNTHESIS, Tetrahedron letters, 39(14), 1998, pp. 1929-1932
Citations number
30
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
14
Year of publication
1998
Pages
1929 - 1932
Database
ISI
SICI code
0040-4039(1998)39:14<1929:POANIH>2.0.ZU;2-Z
Abstract
Dichloroindium hydride was first generated using the transmetalation b etween indium trichloride and tributylstannane at -78 degrees C, and t he generation was confirmed by IR and NMR measurements. The resulting hydride is considerably stable even at ambient temperature due to the coordination of THF, such that it is applicable to practical reduction of carbonyls and halides. (C) 1998 Elsevier Science Ltd. All rights r eserved.