STEREOSELECTIVE SYNTHESIS OF METHYL TRANS-CHRYSANTHEMATE AND RELATED DERIVATIVES

Authors
KRIEF A PROVINS L
Citation
A. Krief et L. Provins, STEREOSELECTIVE SYNTHESIS OF METHYL TRANS-CHRYSANTHEMATE AND RELATED DERIVATIVES, Tetrahedron letters, 39(14), 1998, pp. 2017-2020
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
14
Year of publication
1998
Pages
2017 - 2020
Database
ISI
SICI code
0040-4039(1998)39:14<2017:SSOMTA>2.0.ZU;2-U
Abstract
gamma-hydroxyalkenylstannanes, readily available from alpha,beta-unsat urated esters, alpha,beta-unsaturated aldehydes and tri(n-butyl)stanny llithium, react with boron trifluoride etherate to produce vinyl cyclo propane carboxylic esters. An original highly convergent synthesis of chrysanthemic acid is reported. (C) 1998 Elsevier Science Ltd. All rig hts reserved.