POWDER DIFFRACTION OF [CO(NH3)(5)CO3]NO3-CENTER-DOT-1 2H(2)O AND [CO(NH3)(4)CO3]NO3-CENTER-DOT-1/2H(2)O/

Authors
WU HX ZHU JH MA LD SHEN XL SHI GS
Citation
Hx. Wu et al., POWDER DIFFRACTION OF [CO(NH3)(5)CO3]NO3-CENTER-DOT-1 2H(2)O AND [CO(NH3)(4)CO3]NO3-CENTER-DOT-1/2H(2)O/, Powder diffraction, 13(1), 1998, pp. 32-34
Citations number
7
Categorie Soggetti
Materials Science, Characterization & Testing
Journal title
Powder diffraction → ACNP
ISSN journal
08857156
Volume
13
Issue
1
Year of publication
1998
Pages
32 - 34
Database
ISI
SICI code
0885-7156(1998)13:1<32:PDO[2A>2.0.ZU;2-O
Abstract
Two compounds, [Co(NH3)(5)CO3]NO3 . 1/2H(2)O (labeled A) and [Co(NH3)( 4)CO3]NO3 . 1/2H(2)O (labeled B), were obtained and characterized by X -ray powder diffraction. The samples were indexed using the programs T REOR90 and DICVOL91. In a monoclinic setting, the cell parameters are a=7.6661(3) Angstrom, b=9.6212(3) Angstrom, c=7.0725(4) Angstrom, beta =106.261(4)degrees, V=500.78 Angstrom(3), M-20=36, F-30=65 (0.0106, 44 ) for A and a=10.5623(5) Angstrom, b=22.7304(18) Angstrom, c=7.5174(5) Angstrom, beta=91.350(5)degrees, V=1804.31 Angstrom(3), M-20=36, F-30 =82 (0.0071, 52) for B. The space group is probably P2(1)/m(11) for A and P2(1)/n(14) for B according to their reflection conditions. (C) 19 98 International Centre for Diffraction Data.