Jd. Li et al., PREDICTION OF VAPOR-LIQUID-EQUILIBRIA FOR ASYMMETRIC SYSTEMS AT LOW AND HIGH-PRESSURES WITH THE PSRK MODEL, Fluid phase equilibria, 143(1-2), 1998, pp. 71-82
The idea of effective R-k, Q(k)* for the subgroups CH3, CH2, CH and C
of UNIFAC in PSRK is proposed. Based on this idea, an empirical expre
ssion has been developed, allowing the reliable prediction of vapor-li
quid equilibria for asymmetric systems at low and high pressures with
the help of the PSRK model. Published by Elsevier Science B.V.