NEW APPLICATIONS OF THE ERAS-MODEL - EXCESS VOLUMES OF BINARY-LIQUID MIXTURES OF 1-ALKANOLS WITH ACETONITRILE

The applicability of the ERAS-Model to strong polar systems such as 1- alkanol + acetonitrile was analysed. For this purpose, densities for b inary mixtures of 1-heptanol and l-octanol with acetonitrile have been measured at 293.15, 298.15, and 313.15 K using a vibrating-tube densi meter. Excess molar volumes (V-m(E)) were determined. Both systems exh ibit positive V-m(E) values over the entire composition range in the t emperature range studied. ERAS-Model calculations allowing for self-as sociation for both components alkanol and acetonitrile were performed. The agreement between theoretical and experimental results is satisfa ctory only for the composition central range. A simplified version of the model, without the chemical contribution, gives better results. (C ) 1998 Elsevier Science B.V.