The reactions between polymeric diphenyl methane diisocyanate (polymer
ic MDI) and conventional polyols to produce foamed polyurethane produc
ts are well documented and published. Current polyurethane foams are p
redominantly produced from these reactions whereby the polyol componen
ts are usually obtained from petrochemical processes. This article des
cribes a new development in polyurethane foam technology whereby a ren
ewable source of polyol derived from refined-bleached-deodorized (RED)
palm oil is used to produce polyurethane foams. Using very basic foam
formulation, rigid polyurethane foams were produced with carbon dioxi
de as the blowing agent generated from the reaction between excess pol
ymeric MDI with water. The foams produced from this derivatized RED pa
lm oil have densities in excess of 200 kg/m(3) and with compression st
rengths greater than 1 MPa. (C) 1998 John Wiley & Sons, Inc.